國家衛生研究院 NHRI:Item 3990099045/1132
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    题名: A modified Robinson annulation process to alpha,alpha-disubstituted-beta,gamma-unsaturated cyclohexanone system. Application to the total synthesis of nanaimoal
    其它题名: A modified Robinson annulation process to α,α-disubstituted-β,γ-unsaturated cyclohexanone system. Application to the total synthesis of nanaimoal
    作者: Liu, HJ;Ly, TW;Tai, CL;Wu, JD;Liang, JK;Guo, JC;Tseng, NW;Shia, KS
    贡献者: Division of Biotechnology and Pharmaceutical Research
    摘要: 4-Cyano-2-cyclohexenones were found to be susceptible to reductive alkylation reactions, giving the corresponding 2,2-disubstituted-3-cyclohexenone derivatives in a completely regioselective manner. This newly developed methodology has been successfully applied towards the total synthesis, in racemic form, of the marine natural product nanaimoal. (C) 2003 Elsevier Science Ltd. All rights reserved.
    关键词: Chemistry, Organic
    日期: 2003-02-17
    關聯: Tetrahedron. 2003 Feb;59(8):1209-1226.
    Link to: http://dx.doi.org/10.1016/S0040-4020(03)00034-6
    JIF/Ranking 2023: http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=NHRI&SrcApp=NHRI_IR&KeyISSN=0040-4020&DestApp=IC2JCR
    Cited Times(WOS): https://www.webofscience.com/wos/woscc/full-record/WOS:000181019900010
    Cited Times(Scopus): http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=0037450403
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