國家衛生研究院 NHRI:Item 3990099045/16290
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    题名: Alkoxylation of ketone mediated by N-heterocyclic carbene borane and sulfuric acid in alcohol
    作者: Tanpure, SD;Chang, PW;Ueng, SH
    贡献者: Institute of Biotechnology and Pharmaceutical Research
    摘要: In this study, a novel method for the alkoxylation of ketones has been developed, employing sulfuric acid and N-heterocyclic carbene boranes (NHC−boranes). The ketones are reduced using NHC−borane (diMe-Imd-BH3) and subsequently alkoxylate with sulfuric acid in alcohol solvents. Due to the stability of NHC−borane in the presence of both moisture and air, this reaction emerges as an effective and accessible approach for organic synthesis.
    日期: 2024-09-27
    關聯: Asian Journal of Organic Chemistry. 2024 Sep 27;Article in Press.
    Link to: http://dx.doi.org/10.1002/ajoc.202400436
    JIF/Ranking 2023: http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=NHRI&SrcApp=NHRI_IR&KeyISSN=2193-5815&DestApp=IC2JCR
    Cited Times(WOS): https://www.webofscience.com/wos/woscc/full-record/WOS:001357602400001
    Cited Times(Scopus): https://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85208494405
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