國家衛生研究院 NHRI:Item 3990099045/1130

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Please use this identifier to cite or link to this item: http://ir.nhri.org.tw/handle/3990099045/1130

Title:	Diels-Alder chemistry of 2-diethoxyphosphinylcyclohex-2-enones. A new approach to complex phosphonates and synthetic applications of the beta-keto phosphonate system
Authors:	Chien, CF;Wu, JD;Ly, TW;Shia, KS;Liu, HJ
Contributors:	Division of Biotechnology and Pharmaceutical Research
Abstract:	Enone phosphonates 1 and 2 were found to be excellent dienophiles for the Diels-Alder reaction, giving phosphonate-containing polycycles, and the phosphonate group of the resulting adducts facilitated both the installation of an angular alkyl group via a reductive alkylation process and the regioselective generation of a ring junction double bond via an intramolecular Wadsworth-Horner-Emmons reaction.
Keywords:	Chemistry, Multidisciplinary
Date:	2002
Relation:	Chemical Communications. 2002(3):248-249.
Link to:	http://dx.doi.org/10.1039/b109780f
JIF/Ranking 2023:	http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=NHRI&SrcApp=NHRI_IR&KeyISSN=1359-7345&DestApp=IC2JCR
Cited Times(WOS):	https://www.webofscience.com/wos/woscc/full-record/WOS:000173812200029
Cited Times(Scopus):	http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=0037034084
Appears in Collections:	[Kak-Shan Shia] Periodical Articles

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