國家衛生研究院 NHRI:Item 3990099045/1130
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    题名: Diels-Alder chemistry of 2-diethoxyphosphinylcyclohex-2-enones. A new approach to complex phosphonates and synthetic applications of the beta-keto phosphonate system
    作者: Chien, CF;Wu, JD;Ly, TW;Shia, KS;Liu, HJ
    贡献者: Division of Biotechnology and Pharmaceutical Research
    摘要: Enone phosphonates 1 and 2 were found to be excellent dienophiles for the Diels-Alder reaction, giving phosphonate-containing polycycles, and the phosphonate group of the resulting adducts facilitated both the installation of an angular alkyl group via a reductive alkylation process and the regioselective generation of a ring junction double bond via an intramolecular Wadsworth-Horner-Emmons reaction.
    关键词: Chemistry, Multidisciplinary
    日期: 2002
    關聯: Chemical Communications. 2002(3):248-249.
    Link to: http://dx.doi.org/10.1039/b109780f
    JIF/Ranking 2023: http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=NHRI&SrcApp=NHRI_IR&KeyISSN=1359-7345&DestApp=IC2JCR
    Cited Times(WOS): https://www.webofscience.com/wos/woscc/full-record/WOS:000173812200029
    Cited Times(Scopus): http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=0037034084
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